Here's a decent list of tips. Few things I didn't know... like raising/lowering things in structure mode. You'll notice real quick the game doesn't explain things very well (like the built-in fire-from-cover system).
https://www.reddit.com/r/fo4/comments/3shl9i/fallout_4_tips_everyone_should_know/
https://www.reddit.com/r/fo4/comments/3shl9i/fallout_4_tips_everyone_should_know/