I would bet while more people are electrocuted by 120VAC than anything else, most are burned by arc flash incidents with 480 volts than electrocuted. I've never been hit by 480v but I know guys that have and based on their descriptions, you are right about the "hit" at that voltage level. You start getting up into the 5 digit voltage ranges and you start talking about 4th degree burns.
If you grab 120 with your hand and it is in you palm, the hand contracts from the currant and holds onto the wire until you are knocked or jolted loose. If you are not freed from it you could die. If it hits you on the arm or similar place it just hurts like hell.
277 and up will blow holes in you. I have places where the 440 hit I received jumped out and left some scars. If it had not knocked me off of the ladder not sure how that would have ended for me. Not good I am guessing.
Above 440 you better be properly geared up.