You can lightly sand them so they go in and out smoother but no the magwell will not get broken in.
Are you guys sure it's the mags and not the magazine catch?? Press the mag release button in as far as you can and I bet they will fall out. If that's the case back your mag catch off a turn.
When you say new, do you mean the Rev. M Pmags? If so, all of mine drop free from my Spike's AR.
That really shouldn't be necessary, should it? Is this a known issue or something? I just checked my 6 30-round Pmags as well as 4 20-round Pmags, they all fit just fine, no wobble in the magwell or anything, and they all drop free with a press of the mag release.