6 hours is more than enough. Shake the heck out of it in you media separator.
If you are using "Fine" media I fail to see how media could get stuck inside the cases. They were not wet/moist in any way were they?
I tumble brass by the thousands and since I have discovered "Fine" media which to me is 20/40 grit I have no media stuck anywhere, not even in the primer pocket or flash holes. In fact the media is fine enough to flow thru the flash hole.
Who added the polish? If it was you, was it wet polish and you did not allow it to disperse in the media before tumbling?
no its not a polish issue. I went back and looked at the brass just not, and found that it was limited to one specific case. All the Fiocchi GFL marked brass has the issue, nothing else. I had 50 round of Fiocchi brass in this batch, and all of the other brass was fine. Its something actually inside the case, some burned on black carbon looking stuff that the media is sticking too. I tossed that brass in with the next batch to see if it will clean up or not.